Nuclear Resonance Vibrational Spectroscopy Definition of O2Intermediates in an Extradiol Dioxygenase: Correlation to Crystallography and Reactivity
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چکیده
منابع مشابه
Electron paramagnetic resonance detection of intermediates in the enzymatic cycle of an extradiol dioxygenase.
Extradiol catecholic dioxygenases catalyze the cleavage of the aromatic ring of the substrate with incorporation of both oxygen atoms from O2. These enzymes are important in nature for the recovery of large amounts of carbon from aromatic compounds. The catalytic site contains either Fe or Mn coordinated by a facial triad of two His and one Glu or Asp residues. Previous studies have shown that ...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2018
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.8b06517